An unexpected formation of a Ru(III) benzylidene complex during activation of a LatMet-type ring-opening polymerisation catalyst
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.05.014
Abstract: Abstract Upon activation with C2Cl6 known latent Ru metathesis catalyst LatMet (13) exhibited activity in RCM and in ROMP of DCPD. A by-product of such activation, an aryloxybenzylidene ruthenium(III) complex 17 have been independently synthesised… read more here.
Keywords: iii benzylidene; formation iii; benzylidene complex; unexpected formation ... See more keywords
Complex formation in the Fe(II)-Fe(III)-acrylamide–water system and chemical models
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1766682
Abstract: Abstract This paper investigates complex formation in the Fe(II)-Fe(III)-acrylamide-water system. Dependences of oxidative potentials on the concentration and model parameters of iron acrylamide complexes are discussed. Effect of reaction pH on polymerization of acrylamide and… read more here.
Keywords: formation iii; acrylamide water; iii acrylamide; complex formation ... See more keywords