Zirconium-mediated carbon–carbon bond formation reactions of 1,3-enynes with esters and isocyanates
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121410
Abstract: Abstract Five-membered metallacycloallene compounds, 1-zirconacyclopenta-2,3-dienes 1, derived from but-1-en-3-ynes 2 and low-valent zirconocene, reacted with esters and isocyanates. Reactions of 1 with carboxylic esters such as ethyl acetate and methyl benzoate resulted in the formation… read more here.
Keywords: carbon; bond formation; bond; formation reactions ... See more keywords
A Universal Approach to Quantify Overpotential-Dependent Selectivity Trends for the Competing Oxygen Evolution and Peroxide Formation Reactions: A Case Study on Graphene Model Electrodes
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.1c03323
Abstract: In this article, we study the competing oxygen evolution and hydrogen peroxide (H2O2) formation reactions for periodic models of graphene with different active-site concentrations by means of densi... read more here.
Keywords: competing oxygen; oxygen evolution; study; formation reactions ... See more keywords
Formation and reactions of active five-membered phosphane/borane frustrated Lewis pair ring systems.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00672e
Abstract: The reactive five-membered frustrated P/B Lewis pair 6a was generated from Tipp-P(vinyl)2 (Tipp: 2,4,6-triisopropylphenyl) by a series of anti-Markovnikov and Markovnikov hydroboration reactions. The in situ generated compound dimerized to give 7a under kinetic control… read more here.
Keywords: reactions active; pair; lewis pair; formation reactions ... See more keywords
Sub-barrier quasifission in heavy element formation reactions with deformed actinide target nuclei
Sign Up to like & getrecommendations! Published in 2018 at "Physical Review C"
DOI: 10.1103/physrevc.97.024616
Abstract: The authors acknowledge support from ARC Grants No. FL110100098, No. DP130101569, No. FT120100760, No. DE140100784, No. DP140101337, No. DP160101254, and No. DP170102318, and support by the Federal Government NCRIS program for operations of the ANU… read more here.
Keywords: barrier quasifission; sub barrier; quasifission heavy; heavy element ... See more keywords