Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes
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DOI: 10.1016/j.jorganchem.2019.06.010
Abstract: Abstract The reaction of (4-methyl-pyridine-2-iloxy)dimethylsilane (NSiMe–H, 1) with [RhCl(coe)2]2 gives the rhodium(III) complex [Rh(Cl)(κ2-NSiMe)2] (2), which reacts with a stoichiometric amount of AgCF3CO2 to afford [Rh(κ2-CF3CO2)(κ2-NSiMe)2] (3). Complexes 2 and 3 have been fully characterized… read more here.
Keywords: amines co2; formation silylcarbamates; reaction secondary; secondary amines ... See more keywords