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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03413
Abstract: Herein, we report Ni-catalyzed intramolecular carboacylation of imides containing a tethered alkene and tetraarylborate nucleophiles. Using a nickel-phosphine catalyst system, α-substituted, γ-amino ketones are generated in up to 92% yield with site selectivity. Deprotection and…
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Keywords:
catalyzed formation;
nickel catalyzed;
amino ketones;
substituted amino ... See more keywords