Nickel (II) Mediated In-situ Complex Formation with unexpected Ligand Transformations: Crystal Structures, DFT calculations and Catalytic Activity in CO2 Fixation Reaction
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DOI: 10.1039/d4nj01801j
Abstract: Two transformed ligands namely 1,3,5-triazapentadienato(imidoylamidinato) and N-(methoxy(pyrimidin-2-yl)(pyrimidine-2-carboxamido)methyl)pyrimidine-2-carboxamide which is the first report that are produced from 2-cyano pyridine/pyrimidine respectively under nickel metal mediation in presence of hydroxyl-amine hydrochloride in in-situ... read more here.
Keywords: situ complex; formation unexpected; unexpected ligand; complex formation ... See more keywords