Anchoring and Upgrading Ultrafine NiPd on Room-Temperature-Synthesized Bifunctional NH2 -N-rGO toward Low-Cost and Highly Efficient Catalysts for Selective Formic Acid Dehydrogenation.
Sign Up to like & getrecommendations! Published in 2018 at "Advanced materials"
DOI: 10.1002/adma.201703038
Abstract: Hydrogen is widely considered to be a sustainable and clean energy alternative to the use of fossil fuels in the future. Its high hydrogen content, nontoxicity, and liquid state at room temperature make formic acid… read more here.
Keywords: rgo; room temperature; formic acid; low cost ... See more keywords
Hollow Carbon Nanorod Confined Single Atom Rh for Direct Formic Acid Electrooxidation
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202205299
Abstract: Nearly theoretical 100% atomic utilization (supposing each atom could serve as independent sites to play a role in catalyz) of single‐atom catalysts (SACs) makes it highly promising for various applications. However, for most SACs, single‐atom… read more here.
Keywords: hollow carbon; atom; single atom; formic acid ... See more keywords
Towards closed carbon loop fermentations: co-feeding of Yarrowia lipolytica with glucose and formic acid.
Sign Up to like & getrecommendations! Published in 2022 at "Biotechnology and bioengineering"
DOI: 10.1002/bit.28115
Abstract: A novel fermentation process was developed in which renewable electricity is indirectly used as an energy source in fermentation, synergistically decreasing both the consumption of sugar as a first generation carbon source and emission of… read more here.
Keywords: carbon loop; formic acid; closed carbon; fermentation ... See more keywords
Continuous Hydrogenation of Carbon Dioxide to Formic Acid and Methyl Formate by a Molecular Iridium Complex Stably Heterogenized on a Covalent Triazine Framework
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DOI: 10.1002/cctc.201901179
Abstract: Continuous synthesis of formic acid and methyl formate via CO2 hydrogenation is demonstrated using a molecular iridium complex stably immobilized on a solid covalent triazine framework (CTF) under high‐pressure conditions. Compared to formic acid synthesis,… read more here.
Keywords: methyl formate; acid methyl; formic acid;
Release of Formic Acid from Copper Formate: Hydride, Proton‐Coupled Electron and Hydrogen Atom Transfer All Play their Role
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DOI: 10.1002/cphc.201900095
Abstract: Abstract Although the mechanism for the transformation of carbon dioxide to formate with copper hydride is well understood, it is not clear how formic acid is ultimately released. Herein, we show how formic acid is… read more here.
Keywords: hydrogen atom; copper; formic acid; transfer ... See more keywords
Combining Cost-Efficient Cellulose and Short-Chain Carboxylic Acid Production: The Polyoxometalate (POM)-Ionosolv Concept.
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DOI: 10.1002/cplu.202000025
Abstract: Full cost-effective exploitation of all wood components is key to growing a commercially successful biorefining industry. An innovative process is reported that combines fractionation of lignocellulosic biomass using a low-cost ionic liquid (Ionosolv) and production… read more here.
Keywords: polyoxometalate; ionosolv; formic acid; pom ionosolv ... See more keywords
Formic Acid-Induced Controlled-Release Hydrolysis of Microalgae (Scenedesmus) to Lactic Acid over Sn-Beta Catalyst.
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DOI: 10.1002/cssc.201801087
Abstract: Formic acid-induced controlled-release hydrolysis of sugar-rich microalgae (Scenedesmus) over the Sn-Beta catalyst was found to be a highly efficient process for producing lactic acid as a platform chemical. One-pot reaction with a very high lactic… read more here.
Keywords: catalyst; controlled release; formic acid; hydrolysis ... See more keywords
Synergistic Activation of Palladium Nanoparticles by Polyoxometalate-Attached Melem for Boosting Formic Acid Dehydrogenation Efficiency.
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DOI: 10.1002/cssc.201801521
Abstract: Pd nanoparticles (NPs) anchored on a phosphotungstic acid attached melem porous hybrid (PW/melem) were prepared by hybridization of phosphotungstic acid Pd salt and melem, followed by chemical reduction. PW/melem was demonstrated to be an outstanding… read more here.
Keywords: synergistic activation; attached melem; dehydrogenation; formic acid ... See more keywords
Visible light photocatalytic reduction of CO2 to formic acid with a Ru catalyst supported by an unprecedented ligand array.
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DOI: 10.1002/cssc.201901326
Abstract: Visible light photocatalytic CO2 reduction using a Ru(II) complex supported by N,N'-bis(diphenylphosphino)-2,6-diamino)pyridine ("PNP") ligands, an unprecedented molecular architecture for this reaction, breaks the domination of α-diimine ligands after more than three decades. These competent catalysts… read more here.
Keywords: reduction; co2 formic; light photocatalytic; visible light ... See more keywords
Confinement-enhanced selective oxidation of lignin derivatives to formic acid over Fe-Cu/ZSM-5 catalysts under mild conditions.
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DOI: 10.1002/cssc.202200218
Abstract: Aqueous-phase oxidation by H2O2, known as the Fenton-type process, provides an attractive route to convert recalcitrant lignin derivatives to valuable chemicals under mild conations. The development of this technology is, however, limited by the uncontrolled… read more here.
Keywords: oxidation; formic acid; confinement enhanced; zsm ... See more keywords
Selective oxidation of glycerol into formic acid by photogenerated holes and superoxide radicals.
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DOI: 10.1002/cssc.202201068
Abstract: Photocatalysis is a promising technology for conversion of the glycerol into formic acid, but photocatalytic oxidation of C-C bonds in glycerol exhibits poor selectivity towards formic acid because the photogenerated radicals (e.g., hydroxyl radicals) further… read more here.
Keywords: oxidation; acid photogenerated; formic acid; acid ... See more keywords