High-performance miniature CSTR for biphasic C–C bond-forming reactions
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2017.10.114
Abstract: Chemical transformations used in fine chemical manufacturing often involve two-phase interaction for which mass transfer limitations can lead to prolonged reaction time and reduced productivity. We present a high-performance miniature continuous stirred-tank reactor (CSTR), with… read more here.
Keywords: cstr; performance miniature; forming reactions; biphasic bond ... See more keywords
Exploring the influence of designer surfactant hydrophobicity in key C C/C N bond forming reactions
Sign Up to like & getrecommendations! Published in 2019 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2019.01.006
Abstract: Abstract Designer micellar medium was explored for the transformation of diverse anilines to the corresponding densely substituted biologically relevant skatole derivatives in an aqueous medium via 5-exo-trig cyclization reaction. The scope of the reaction was… read more here.
Keywords: designer; bond forming; hydrophobicity; exploring influence ... See more keywords
Multimetallic-Catalyzed C-C Bond-Forming Reactions: From Serendipity to Strategy.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08615
Abstract: The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access complex targets efficiently and selectively from simple starting materials. While capable of uniting distinct reactivities, the principles… read more here.
Keywords: catalyzed bond; forming reactions; multimetallic catalyzed; strategy ... See more keywords
Cobalt-Catalyzed Diastereo- and Enantioselective Carbon-Carbon Bond Forming Reactions of Cyclobutenes.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12475
Abstract: Catalytic enantioselective functionalization of cyclobutenes constitutes a general and modular strategy for construction of enantioenriched complex cyclobutanes bearing multiple stereogenic centers, as chiral four-membered rings are common motifs in biologically active molecules and versatile intermediates… read more here.
Keywords: cobalt catalyzed; carbon bond; carbon; forming reactions ... See more keywords
Palladium catalyzed C–C and C–N bond forming reactions: an update on the synthesis of pharmaceuticals from 2015–2020
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo01146k
Abstract: Some of the most prominent and promising catalysts in organic synthesis for the requisite construction of C–C and C–N bonds are palladium (Pd) catalysts, which play a pivotal role in pharmaceutical and medicinal chemistry. read more here.
Keywords: synthesis; chemistry; forming reactions; palladium catalyzed ... See more keywords
Green Approach toward Triazole forming Reactions for Developing Anticancer Drugs.
Sign Up to like & getrecommendations! Published in 2023 at "Current organic synthesis"
DOI: 10.2174/1570179420666230508125144
Abstract: Compounds containing triazole have many significant applications in the dye and ink industry, corrosion inhibitors, polymers, and pharmaceutical industries. These compounds possess many antimicrobial, antioxidant, anticancer, antiviral, anti-HIV, antitubercular, and anticancer activities. Several synthetic methods… read more here.
Keywords: forming reactions; toward triazole; green approach; approach toward ... See more keywords
Synergistic Action of Copper Catalysts and Lewis Acids in Carbon-Carbon Bond Forming Reactions.
Sign Up to like & getrecommendations! Published in 2018 at "Chimia"
DOI: 10.2533/chimia.2018.642
Abstract: Combining Lewis acids with copper catalysis and highly reactive Grignard reagents allows fine tuning of the reactivity and selectivity of both inherently unreactive and highly reactive electrophilic substrates in asymmetric C-C bond forming reactions. In… read more here.
Keywords: carbon; copper; forming reactions; lewis acids ... See more keywords
Bond Forming Reactions Involving Isocyanides at Diiron Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Inorganics"
DOI: 10.3390/inorganics7030025
Abstract: The versatility of isocyanides (CNR) in organic chemistry has been tremendously enhanced by continuous advancement in transition metal catalysis. On the other hand, the urgent need for new and more sustainable synthetic strategies based on… read more here.
Keywords: reactions involving; isocyanides diiron; diiron complexes; bond forming ... See more keywords