How does binuclear zinc amidohydrolase FwdA work in the initial step of methanogenesis: From formate to formyl-methanofuran.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2018.05.004
Abstract: The initial step of methanogenesis is the fixation of CO2 to formyl-methanofuran (formyl-MFR) catalyzed by formyl-MFR dehydrogenase, which can be divided into two half reactions. Herein, the second half reaction catalyzed by FwdA (formyl-methanofuran dehydrogenase… read more here.
Keywords: zinc; initial step; formate; formyl ... See more keywords
Formyl C-H activation in N,N-Dimethylformamide by a dirhenium carbonyl complex
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.03.009
Abstract: Abstract The reaction of Re2(CO)8[μ-η2-C(H)=C(H)Bun](μ-H), 1 with N,N-dimethylformamide (DMF) at 70 C for 6 h has yielded three new compounds: Re2(CO)8(μ-η2-O=CNMe2)(μ-H), 2, (16% yield), Re2(CO)7(NHMe2)(μ-η2-O=CNMe2)(μ-H), 3, (30% yield), Re2(CO)9(NHMe2), 4 (14% yield). Compounds 2 and 3 contain… read more here.
Keywords: re2; compound; reaction; yield ... See more keywords
Adsorption, micellization and antimicrobial activity of formyl-containing cationic surfactant in diluted aqueous solutions
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2020.115168
Abstract: Abstract Surfactants based on dynamic covalent bonds have attracted significant interest over the past few decades due to the coexistence of covalent and non-covalent bonds. However, studies on the fundamental properties of their precursors are… read more here.
Keywords: formyl containing; containing cationic; antimicrobial activity; micellization ... See more keywords
Accessing the main-group metal formyl scaffold through CO-activation in beryllium hydride complexes
Sign Up to like & getrecommendations! Published in 2022 at "Nature Communications"
DOI: 10.1038/s41467-022-28095-0
Abstract: Carbon monoxide (CO) is an indispensable C1 building block. For decades this abundant gas has been employed in hydroformylation and Pausen-Khand catalysis, amongst many related chemistries, where a single, non-coupled CO fragment is delivered to… read more here.
Keywords: chemistry; beryllium; main group; formyl ... See more keywords
Synthesis, structure, and properties of palladium(II) complex of α-formyl pyrrolyl dipyrromethene.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00166g
Abstract: A simple α-formyl pyrrolyl dipyrromethene ligand was synthesized by deboronation of a BF2 complex of α-formyl pyrrolyl dipyrrin under Lewis acid catalyzed conditions. The α-formyl pyrrolyl dipyrrin ligand was treated with PdCl2 in CH3CN/Et3N at… read more here.
Keywords: pyrrolyl dipyrromethene; pyrrolyl dipyrrin; formyl; formyl pyrrolyl ... See more keywords
Rotational Barriers in N-Benzhydrylformamides: An NMR and DFT Study
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28020535
Abstract: N-Benzhydrylformamides are pharmacologically active compounds with anticonvulsant, enzyme-inducing, antihypoxic, and other types of biological activity. The conformational behavior of benzhydrylformamides is determined to a great extent by the presence of substituents at the nitrogen atom… read more here.
Keywords: bhfa nme; ortho; rotational barriers; formyl ... See more keywords
Morita–Baylis–Hillman reaction of 3-formyl-9H-pyrido[3,4-b]indoles and fluorescence studies of the products
Sign Up to like & getrecommendations! Published in 2022 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.18.92
Abstract: β-Carboline is a privileged class of the alkaloid family and is associated with a broad spectrum of biological properties. 3-Formyl-9H-pyrido[3,4-b]indole is a such potent precursor belonging to this family which can be tailored for installing… read more here.
Keywords: morita baylis; hillman reaction; formyl pyrido; baylis hillman ... See more keywords