Four-Coordinate Organoboron Platforms for Efficient Red Phosphorescent Organic Light-Emitting Diodes.
Sign Up to like & getrecommendations! Published in 2019 at "ChemPlusChem"
DOI: 10.1002/cplu.201900406
Abstract: So far both three- and four-coordinate organoboron compounds have been widely applied in organic light-emitting diode (OLED) materials. However, the use of four-coordinate organoboron compounds as host materials is rarely reported. In this work, two… read more here.
Keywords: organoboron; coordinate organoboron; four coordinate; organoboron compounds ... See more keywords
Cyanide-Bridged Fe-Co Polynuclear Clusters Based on Four-Coordinate Cobalt(II).
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00233
Abstract: Treatment of CoCl2·6H2O and tris(pyrazolyl-1-yl)borate tricyanoiron(III) anions at 55 °C afforded a series of new Fe-Co polynuclear clusters: {Co2Cl2(DMF)4[(Tp4-Me)Fe(CN)3]2} (1; Tp4-Me = hydridotris(4-methylpyrazol-1-yl)borate), (H3O+)@{Co4Cl4[(Tp4-Me)Fe(CN)3]4} (2), (MePh3P)4{Co6Cl6[(Tp4-Me)Fe(CN)3]6}·15CH3CN·3CH3OH·2H2O (3), and (BnEt3N)4{Co5Cl8[(Tp*)Fe(CN)3]4}·4CH3CN·2H2O (4; Tp*= hydridotris(3,5-dimethylpyrazol-1-yl)borate). They feature an… read more here.
Keywords: cobalt; cyanide bridged; polynuclear clusters; geometry ... See more keywords
Monoradical-containing four-coordinate Co(iii) complexes: homolytic S-S and Se-Se bond cleavage and catalytic isocyanate to urea conversion under sunlight.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc03486e
Abstract: Four-coordinate, monoradical-containing Co(iii) complexes participated in the non-innocent ligand driven homolytic cleavage of S-S and Se-Se bonds and catalyzed the conversion of RNCO (R = phenyl and naphthyl) to the corresponding urea derivatives (TON 480)… read more here.
Keywords: monoradical containing; iii complexes; four coordinate; cleavage ... See more keywords
Photochromic dithienylethene-containing four-coordinate boron(III) compounds with a spirocyclic scaffold.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00107a
Abstract: A new series of four-coordinate boron compounds bearing a photochromic dithienylethene-containing C^C ligand and an ancillary N^C ligand have been successfully designed and synthesised. These compounds exhibit reversible photochromism upon photoexcitation with percentage conversions of… read more here.
Keywords: four coordinate; dithienylethene containing; photochromic dithienylethene; coordinate boron ... See more keywords
A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01608k
Abstract: A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ2-hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In… read more here.
Keywords: tetranuclear magnesium; four coordinate; geometry; hydride ... See more keywords