Four-electron reduction of dioxygen to water by a trinuclear copper complex
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.11.014
Abstract: Abstract The synthesis and characterization of a trinuclear copper complex 1 involving an amine based ligand system, tateb , are reported. Complex 1 acts as a catalyst for a four-electron four-proton reduction of dioxygen to… read more here.
Keywords: four electron; copper complex; copper; trinuclear copper ... See more keywords
Four Electron Aromaticity in η3-Allyltetrylenes Ar-E-η3-Allyl E= Si, Ge, Sn, Pb
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.130735
Abstract: Abstract The electronic structure and the conjugation in allyltetrylenes Ar-E-η3-C3H4 (E= Si, Ge, Sn, Pb; Ar = С6H3Trip2 (1), Ph (1′)), which exhibit the unique symmetric η3-coordination among the allyl compounds of the main groups, were studied… read more here.
Keywords: electron; electron aromaticity; aromaticity allyltetrylenes; four electron ... See more keywords
Catalytic Four-Electron Reduction of Dioxygen by Ferrocene Derivatives with a Nonheme Iron(III) TAML Complex.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02400
Abstract: A mononuclear nonheme iron(III) complex with a tetraamido macrocyclic ligand (TAML), [(TAML)FeIII]- (1), is a selective precatalyst for four-electron reduction of dioxygen by ferrocene derivatives in the presence of acetic acid (CH3COOH) in acetone. This… read more here.
Keywords: four electron; electron reduction; ferrocene derivatives; taml ... See more keywords
Mechanisms of Two-Electron and Four-Electron Electrochemical Oxygen Reduction Reactions at Nitrogen-Doped Reduced Graphene Oxide
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b04106
Abstract: Doped carbon-based systems have been extensively studied over the past decade as active electrocatalysts for both the two-electron (2e–) and four-electron (4e–) oxygen reduction reactions (ORRs). H... read more here.
Keywords: four electron; reduction reactions; electron four; two electron ... See more keywords
Carbon's Three-Center, Four-Electron Tetrel Bond, Treated Experimentally.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b09367
Abstract: Tetrel bonding is the noncovalent interaction of group IV elements with electron donors. It is a weak, directional interaction that resembles hydrogen and halogen bonding yet remains barely explored. Herein, we present an experimental investigation… read more here.
Keywords: four electron; bond; tetrel bond; three center ... See more keywords
Single metal four-electron reduction by U(ii) and masked “U(ii)” compounds†
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc00668a
Abstract: The redox chemistry of uranium is dominated by single electron transfer reactions while single metal four-electron transfers remain unknown in f-element chemistry. Here we show that the oxo bridged diuranium(iii) complex [K(2.2.2-cryptand)]2[{((Me3Si)2N)3U}2(μ-O)], 1, effects the… read more here.
Keywords: four electron; electron reduction; chemistry; single metal ... See more keywords