Designing Catalytic Systems Using Binary Solvent Mixtures: Impact of Mole Fraction of Water on Hydride Transfer.
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DOI: 10.1021/acs.inorgchem.1c02397
Abstract: The free energy for hydride transfer reactions of transition metal hydrides is known to be influenced by solvent effects. The first-row transition metal hydride [HNi(dmpe)2][BF4] (dmpe = 1,2-bis(dimethylphosphino)ethane) has starkly different hydride transfer reactivities with… read more here.
Keywords: fraction water; hydride; mole fraction; hydride transfer ... See more keywords