Sterically Induced Ligand Framework Distortion Effects on Catalytic Cyclic Ester Polymerizations.
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DOI: 10.1021/acs.inorgchem.8b00250
Abstract: Aluminum alkoxide complexes supported by salen ligands [salen = N, N'-bis(salicylaldimine)-2-methylpropane-1,2-diamine or N, N'-bis(salicylaldimine)-2,2-dimethylpropane-1,3-diamine] with o-adamantyl substituents have been synthesized and investigated for the polymerization of ε-caprolactone. Geometric analysis of the catalysts used for the… read more here.
Keywords: framework distortion; distortion effects; sterically induced; induced ligand ... See more keywords