Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03504
Abstract: Three polyoxometalate-based metal-organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)3]2+ photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity. The… read more here.
Keywords: photooxidation; frameworks efficient; lanthanide anderson; anderson ... See more keywords
Covalent Organic Frameworks as Efficient Photoinitiators and Cross-Linkers To Fabricate Highly Stretchable Hydrogels.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c17114
Abstract: In this work, two kinds of imine-type covalent organic framework (COF) nanoparticles are demonstrated as efficient photocatalytic initiators to trigger the free-radical polymerization of acrylamide (AM) to prepare polyacrylamide (PAM) hydrogels under visible light irradiation,… read more here.
Keywords: highly stretchable; frameworks efficient; organic frameworks; covalent organic ... See more keywords
Macro/Microporous Covalent Organic Frameworks for Efficient Electrocatalysis.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b01226
Abstract: Covalent organic frameworks (COFs) are of interest for many applications originating from their mechanically robust architectures, low density, and high accessible surface area. Depending on their linkers and binding patterns, COFs mainly exhibit microporosity, even… read more here.
Keywords: frameworks efficient; macro microporous; microporous covalent; organic frameworks ... See more keywords
Partial quaternization promoted metal-organic frameworks for efficient photocatalytic removal of chromium(VI).
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06563k
Abstract: A one-step strategy is applied to partially quaternize the ligand of UiO-66-NH2, and the resultant UiO-66-N(CH3)3+ showed greatly improved photocatalytic performance for Cr(VI) reduction, with the apparent reaction rate constant k increasing by 8.3 times.… read more here.
Keywords: promoted metal; quaternization promoted; partial quaternization; organic frameworks ... See more keywords
Metal-Organic Frameworks as the Efficient Pickering Interfacial Catalyst for Deacetalization-Knoevenagel Tandem Reaction
Sign Up to like & getrecommendations! Published in 2023 at "New Journal of Chemistry"
DOI: 10.1039/d3nj00788j
Abstract: Stabilizing Pickering emulsions with solid catalysts at the oil-water interface is one of the most effective ways to develop environmentally friendly chemical processes. In this study, metal-organic frameworks (ZIF-8, UiO-66(Zr)-NH2,... read more here.
Keywords: frameworks efficient; organic frameworks; metal organic; interfacial catalyst ... See more keywords