Nitrogen-Doped Biomass Carbons Meet with Polyoxometalates: Synergistic Catalytic Reductant-Free Aerobic Hydroxylation of Benzene to Phenol
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b05920
Abstract: A nitrogen-doped biomass carbon catalyst SFNC(800) was prepared by carbonizing the cheap and readily available soybean flour as the starting material at 800 °C. By combining the SFNC(800) with the Keggin-type V-containing polyoxometalate Ch5PMoV2, a… read more here.
Keywords: benzene; nitrogen doped; doped biomass; reductant free ... See more keywords
Metal-free aerobic oxidative direct C–H amination of electron-deficient alkenes via photoredox catalysis
Sign Up to like & getrecommendations! Published in 2018 at "Organic chemistry frontiers"
DOI: 10.1039/c8qo00161h
Abstract: The first example of photocatalytic dehydrogenative cross-coupling of electron-poor alkenes with azoles has been reported. This method provides a novel approach for N-vinylazole synthesis, which enables coupling of a broad scope of azoles and electron-deficient… read more here.
Keywords: deficient alkenes; aerobic oxidative; electron deficient; free aerobic ... See more keywords