Metal-Free S-Arylation of Phosphorothioate Diesters and Related Compounds with Diaryliodonium Salts
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DOI: 10.1021/acs.orglett.2c04310
Abstract: We developed a direct metal-free S-arylation of phosphorothioate diesters using diaryliodonium salts. The method allows for the preparation under simple conditions of a broad range of S-aryl phosphorothioates, including complex molecules (e.g., dinucleotide or TADDOL… read more here.
Keywords: metal free; free arylation; phosphorothioate diesters; diaryliodonium salts ... See more keywords
Boron-catalysed transition-metal-free arylation and alkenylation of allylic alcohols with boronic acids
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DOI: 10.1039/d2ra07919d
Abstract: The development of efficient catalytic reactions with excellent atom and step economy employing sustainable catalysts is highly sought-after in chemical synthesis to reduce the negative effects on the environment. The most commonly-used strategy to construct… read more here.
Keywords: metal free; transition metal; free arylation; arylation alkenylation ... See more keywords