Visible light-mediated metal-free atom transfer radical polymerization with N-trifluoromethylphenyl phenoxazines
Sign Up to like & getrecommendations! Published in 2019 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2019.05.023
Abstract: Abstract The metal-free atom transfer radical polymerization (ATRP) process mediated by visible light and catalyzed by new organic photocatalysts (PCs) is investigated. The new PCs, designed by diversifying N-trifluoromethylphenyl phenoxazine, are analyzed and evaluated for… read more here.
Keywords: free atom; radical polymerization; transfer radical; atom transfer ... See more keywords
Aqueous Metal-Free Atom Transfer Radical Polymerization: Experiments and Model-Based Approach for Mechanistic Understanding
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecules"
DOI: 10.1021/acs.macromol.8b00348
Abstract: Metal-free atom transfer radical polymerization (ATRP) was successfully achieved in aqueous media for the first time. Polymerization of poly(ethylene oxide) methyl ether acrylate (PEGA480) was well controlled (Đ < 1.40) under visible light irradiation using… read more here.
Keywords: atom transfer; free atom; polymerization; radical polymerization ... See more keywords
Free-atom-like d states beyond the dilute limit of single-atom alloys
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d2sc05772g
Abstract: Through a data-mining and high-throughput density functional theory approach, we identify a diverse range of metallic compounds that are predicted to have transition metals with “free-atom-like” d states that are highly localized in terms of… read more here.
Keywords: free atom; limit single; atom; dilute limit ... See more keywords