Ligand-Enabled β-C(sp3)-H Olefination of Free Carboxylic Acids.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b06527
Abstract: An acetyl-protected aminoethyl phenyl thioether has been developed to promote C(sp3)-H activation. Significant ligand enhancement is demonstrated by the realization of the first Pd(II)-catalyzed olefination of C(sp3)-H bonds of free carboxylic acids without using an… read more here.
Keywords: sp3 olefination; free carboxylic; enabled sp3; carboxylic acids ... See more keywords
Superior adsorptive removal of anionic dyes by MIL-101 analogues: the effect of free carboxylic acid groups in the pore channels
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DOI: 10.1039/c9ce01224a
Abstract: MIL-101-COOH nanoparticles functionalized with free carboxylic acid groups exhibited superior CR, MO, and AC adsorption capacities via their distinctive adsorption mechanisms. read more here.
Keywords: free carboxylic; superior adsorptive; acid groups; carboxylic acid ... See more keywords
Pd-catalysed C–H functionalisation of free carboxylic acids
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DOI: 10.1039/d1sc05392b
Abstract: Pd-catalysed C–H functionalisation of free carboxylic acids has drawn significant attention over the last few years due to the predominance of carboxylic acid moieties in pharmaceuticals and agrochemicals. But their coordinating ability was overlooked and… read more here.
Keywords: free carboxylic; functionalisation free; catalysed functionalisation; carboxylic acids ... See more keywords