Catalyst-Free Decarboxylative Amination of Carboxylic Acids in Water Microdroplets.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12236
Abstract: Previous studies have shown that hydroxyl radicals can be formed at the water-gas surface of water microdroplets. We report the use of in situ generated hydroxyl radicals to carry out an organic transformation in one… read more here.
Keywords: decarboxylative amination; free decarboxylative; catalyst free; water ... See more keywords
Transition-metal-free decarboxylative bromination of aromatic carboxylic acids††Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc01016a
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DOI: 10.1039/c8sc01016a
Abstract: Aromatic acids are converted into aryl bromides simply and efficiently via decarboxylation providing new depth and insight into Hunsdiecker-type reactivity. read more here.
Keywords: transition metal; aromatic carboxylic; bromination aromatic; metal free ... See more keywords