Electrooxidative Metal‐Free Dehydrogenative α‐Sulfonylation of 1H‐Indole with Sodium Sulfinates
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201700269
Abstract: A method for the electrochemical α-sulfonylation of 1H-indole with arenesulfinates was developed. A variety of indoles underwent this sulfonylation smoothly at room temperature under metal-free and chemical-oxidant-free conditions to afford indolyl aryl sulfones in good… read more here.
Keywords: electrooxidative metal; sulfonylation; dehydrogenative sulfonylation; sulfonylation indole ... See more keywords
Photo-induced metal-free dehydrogenative N-N homo-coupling.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04204e
Abstract: We report a photo-induced dehydrogenative N-N coupling of diarylimines, diarylamines, carbazoles, and anilines. These homo-coupling reactions require only the combination of readily available di-tert-butyl peroxide (DTBP) and light irradition. The operationally simple protocol works under… read more here.
Keywords: photo; metal free; photo induced; homo coupling ... See more keywords