Synthesis of Poly(phenyltriazolylcarboxylate)s with Aggregation-Induced Emission Characteristics by Metal-Free 1,3-Dipolar Polycycloaddition of Phenylpropiolate and Azides.
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DOI: 10.1002/marc.201600745
Abstract: Two soluble poly(phenyltriazolylcarboxylate)s (PPTCs) with high molecular weights (M w up to 26 800) are synthesized by the metal-free 1,3-dipolar polycycloadditions of 4,4'-isopropylidenediphenyl diphenylpropiolate (1) and tetraphenylethene-containing diazides (2) in dimethylformamide at 150 °C for… read more here.
Keywords: aggregation; aggregation induced; poly phenyltriazolylcarboxylate; metal free ... See more keywords
A catalyst-free 1,3-dipolar cycloaddition of C,N-cyclic azomethine imines and 3-nitroindoles: an easy access to five-ring-fused tetrahydroisoquinolines
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DOI: 10.1039/c6gc02517j
Abstract: We have reported herein a catalyst-free 1,3-dipolar cycloaddition of C,N-cyclic azomethine imines and 3-nitroindoles by which a series of five-ring-fused tetrahydroisoquinolines featuring an indoline scaffold were obtained as single diastereomers in moderate to high yields… read more here.
Keywords: cyclic azomethine; azomethine imines; cycloaddition cyclic; catalyst free ... See more keywords