Aqueous metal-free hydrothiolation of enamides and enecarbamates
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.150951
Abstract: Abstract An efficient and metal-free, anti-Markovnikov selective, hydrothioaltion reaction of enamides and enecarbamates in an aqueous medium is presented. This protocol is operationally simple, mild, and atom-economical. This process provides access to thioethers from available… read more here.
Keywords: free hydrothiolation; aqueous metal; metal free; hydrothiolation enamides ... See more keywords
Catalyst-free hydrothiolation of alkynes with dithiocarbamic acids.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc09726g
Abstract: A highly regio- and stereocontrolled procedure for the synthesis of vinyl dithiocarbamates via catalyst-free hydrothiolation of unactivated alkynes with in situ prepared dithiocarbamic acids with total atom economy is reported. While unactivated terminal alkynes afforded… read more here.
Keywords: dithiocarbamic acids; free hydrothiolation; hydrothiolation alkynes; alkynes dithiocarbamic ... See more keywords