Metal-free photo-induced radical C-P and C-S bond formation for the synthesis of 2-phosphoryl benzothiazoles
Sign Up to like & getrecommendations! Published in 2020 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2019.10.022
Abstract: Abstract We reveal here a visible-light promoted phosphorylation of 2-isocyanoaryl thioethers for the first time with concomitant C(sp3)-S bond cleavage and imidoyl C–S formation. Additionally, this method features the use of 3 mol% organic dye Rose… read more here.
Keywords: phosphoryl benzothiazoles; bond; formation; free photo ... See more keywords
Metal-free and photo-controlled fabrication of fluorinated anti-fouling film
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DOI: 10.1016/j.polymer.2019.122073
Abstract: Abstract We reported a new photo-controlled synthesis route to fabricate a fluorine-containing thin film for protecting the oxidation of indium tin oxide (ITO) and other derivatives such as the fluorine-doped tin oxide (FTO) coated glasses.… read more here.
Keywords: anti fouling; free photo; metal free; film ... See more keywords
Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.941016
Abstract: A photo-induced C-S radical cross-coupling of aryl iodides and disulfides under transition-metal and external photosensitizer free conditions for the synthesis of aryl sulfides at room temperature has been presented, which features mild reaction conditions, broad… read more here.
Keywords: photo; free photo; metal free; photo induced ... See more keywords