Buffer‐Mediated Catalyst‐Free Strecker Reaction Toward Enzymatic Implementation
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DOI: 10.1002/open.202500389
Abstract: A systematic investigation of the catalyst‐free Strecker reaction is conducted in aqueous buffer, offering an efficient and green alternative that leads to α‐aminonitriles without the need of chromatography. Optimization reveals that low pH and high… read more here.
Keywords: reaction; free strecker; catalyst free; buffer ... See more keywords
Polyaromatic Group Embedded Cd(II)-Coordination Polymers for Microwave-Assisted Solvent-Free Strecker-Type Cyanation of Acetals
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DOI: 10.3390/molecules28030945
Abstract: In this work, two new 1D Cd(II) coordination polymers (CPs), [Cd(L1)(NMF)2]n (1) and [Cd(L2)(DMF)(H2O)2]n·n(H2O) (2), have been synthesized, characterized and employed as catalysts for the microwave-assisted solvent-free Strecker-type cyanation of different acetals. Solvothermal reaction between… read more here.
Keywords: free strecker; coordination; solvent free; strecker type ... See more keywords