(Planar‐Chiral) Ferrocenylmethanols: From Anionic Homo Phospho‐Fries Rearrangements to α‐Ferrocenyl Carbenium Ions
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DOI: 10.1002/ejic.201700645
Abstract: The reaction of FcCH2OH with chlorophosphates gave ferrocenyl phosphates FcCH2OP(O)(OR)2 (Fc = Fe(η5-C5H5)(η4-C5H4)), which readily separate into phosphate anions and ferrocenyl carbo-cations. The latter species undergoes consecutive reactions, e. g. electrophilic aromatic substitutions. When nitriles,… read more here.
Keywords: phospho fries; anionic homo; homo phospho; fries rearrangements ... See more keywords