Controllable Frontal Polymerization and Spontaneous Patterning Enabled by Phase-Changing Particles.
Sign Up to like & getrecommendations! Published in 2021 at "Small"
DOI: 10.1002/smll.202102217
Abstract: Frontal polymerization provides a rapid, economic, and environmentally friendly methodology to manufacture thermoset polymers and composites. Despite its efficiency and reduced environmental impact, the manufacturing method is underutilized due to the limited fundamental understanding of… read more here.
Keywords: polymerization; frontal polymerization; controllable frontal; patterning enabled ... See more keywords
Frontal polymerization and characterization of interpenetrating polymer networks composed of poly(N-isopropylacrylamide) and polyvinylpyrrolidone
Sign Up to like & getrecommendations! Published in 2017 at "Colloid and Polymer Science"
DOI: 10.1007/s00396-017-4215-5
Abstract: The synthesis of semi-interpenetrating polymer networks (IPN) of the hydrogel, poly(N-isopropylacrylamide)/polyvinylpyrrolidone (PNIPAm/PVP), by frontal polymerization, was carried out. The frontal parameters were studied, and the products were characterized. It was observed that the incorporation of… read more here.
Keywords: polymer networks; frontal polymerization; drug; poly isopropylacrylamide ... See more keywords
Manufacturing of unidirectional glass-fiber-reinforced composites via frontal polymerization: A numerical study
Sign Up to like & getrecommendations! Published in 2019 at "Composites Science and Technology"
DOI: 10.1016/j.compscitech.2019.107832
Abstract: Abstract Frontal polymerization (FP) is explored as a faster and energy-efficient manufacturing method for dicyclopentadiene (DCPD) matrix, E-glass-fiber-reinforced composites through a series of numerical simulations based on a homogenized reaction-diffusion model. The simulations are carried… read more here.
Keywords: frontal polymerization; glass; fiber reinforced; fiber ... See more keywords
Frontal Polymerizations: From Chemical Perspectives to Macroscopic Properties and Applications
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Reviews"
DOI: 10.1021/acs.chemrev.2c00686
Abstract: The synthesis and processing of most thermoplastics and thermoset polymeric materials rely on energy-inefficient and environmentally burdensome manufacturing methods. Frontal polymerization is an attractive, scalable alternative due to its exploitation of polymerization heat that is… read more here.
Keywords: frontal polymerizations; chemical perspectives; polymerizations chemical; frontal polymerization ... See more keywords
Switching Frontal Polymerization Mechanisms: FROMP and FRaP.
Sign Up to like & getrecommendations! Published in 2022 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.2c00393
Abstract: Two frontal polymerization (FP) mechanisms, frontal ring-opening metathesis polymerization (FROMP) of dicyclopentadiene and frontal radical polymerization (FRaP) of benzyl acrylate and hexanediol diacrylate, were combined for rapid manufacturing of welded thermoset materials. Leveraging the immiscibility… read more here.
Keywords: polymerization mechanisms; switching frontal; frap; frontal polymerization ... See more keywords
Microstructural study of epoxy-based thermosets prepared by “classical” and cationic frontal polymerization
Sign Up to like & getrecommendations! Published in 2020 at "RSC Advances"
DOI: 10.1039/d0ra08298h
Abstract: Epoxides prepared by cationic frontal polymerization have a greater reduced void fraction than “classically” cured samples revealing free-volume consequences of waves. read more here.
Keywords: frontal polymerization; cationic frontal; study epoxy; epoxy based ... See more keywords
Preparation of novel β-CD/P(AA-co-AM) hydrogels by frontal polymerization
Sign Up to like & getrecommendations! Published in 2023 at "RSC Advances"
DOI: 10.1039/d2ra07649g
Abstract: In this paper, betaine (Bet) was used as a hydrogen bond acceptor (HBA), and acrylic acid (AA) and acrylamide (AM) were used as hydrogen bond donors (HBD) and mixed to form a deep eutectic solvent… read more here.
Keywords: novel hydrogels; preparation novel; hydrogels frontal; frontal polymerization ... See more keywords
Preparation of P(AM-co-MA) composite hydrogels by frontal polymerization and its performance study
Sign Up to like & getrecommendations! Published in 2023 at "New Journal of Chemistry"
DOI: 10.1039/d3nj01084h
Abstract: Deep eutectic solvent (DES) was synthesized from choline chloride (ChCl) and acrylamide (AM), and P(AM-co-MA) hydrogels were prepared by adding different contents of maleic acid (MA) to DES by frontal... read more here.
Keywords: polymerization performance; composite hydrogels; performance study; hydrogels frontal ... See more keywords
Preparation of SA/P(U-AM-ChCl) composite hydrogels by frontal polymerization and its performance study
Sign Up to like & getrecommendations! Published in 2023 at "RSC Advances"
DOI: 10.1039/d3ra01478a
Abstract: Deep eutectic solvent (DES) was synthesized from urea (U), acrylamide (AM) and choline chloride (ChCl), sodium alginate (SA) was selected as filler, and SA/P(U-AM-ChCl) composite hydrogel was prepared by thermal initiation frontal polymerization (FP). The… read more here.
Keywords: composite hydrogels; preparation; chcl composite; frontal polymerization ... See more keywords
Anisotropic frontal polymerization in a model resin-copper composite.
Sign Up to like & getrecommendations! Published in 2022 at "Chaos"
DOI: 10.1063/5.0077552
Abstract: This work investigates experimentally and numerically frontal polymerization in a thermally anisotropic system with parallel copper strips embedded in 1,6-hexanediol diacrylate resin. Both experiments and multiphysics finite element analyses reveal that the front propagation in… read more here.
Keywords: system; anisotropic frontal; resin; model ... See more keywords
Facile Obtainment of Fluorescent PEG Hydrogels Bearing Pyrene Groups by Frontal Polymerization
Sign Up to like & getrecommendations! Published in 2023 at "Polymers"
DOI: 10.3390/polym15071687
Abstract: Frontal polymerization (FP) was used to prepare poly(ethylene glycol) methyl ether acrylate (PEGMA) fluorescent polymer hydrogels containing pyrenebutyl pendant groups as fluorescent probes. The polymerization procedure was carried out under solvent-free conditions, with different molar… read more here.
Keywords: obtainment fluorescent; fluorescent peg; facile obtainment; frontal polymerization ... See more keywords