B-H and O-H bonds activation via a single electron transfer of frustrated radical pairs.
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DOI: 10.1039/d1dt01169c
Abstract: The rare examples of B-H bond activation in a frustrated radical pair regime have been observed by treatment of TEMPO radicals with Piers' borane HB(C6F5)2 or bis-borane, respectively. The resulting concomitant formation of zwitterionic products… read more here.
Keywords: frustrated radical; single electron; electron transfer; activation via ... See more keywords