Ni(I)-Hydride Catalyst for Hydrosilylation of Carbon Dioxide and Dihydrogen Generation: Theoretical Prediction and Exploration of Full Catalytic Cycle
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DOI: 10.1021/acs.organomet.8b00011
Abstract: We wish to report here the first theoretical prediction that a unique nickel(I) hydride complex NiIH(bpy) (bpy = 2,2′-bipyridine) 1 is a good catalyst for hydrosilylation of CO2 with hydrosilane (HSiR3) and dihydrogen (H2) generation… read more here.
Keywords: full catalytic; catalyst hydrosilylation; dihydrogen generation; theoretical prediction ... See more keywords