[60]Fullerene-Fused Cyclopentanes: Mechanosynthesis and Photovoltaic Application.
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DOI: 10.1021/acs.orglett.3c00332
Abstract: The mechanochemical cascade reaction of [60]fullerene with 3-benzylidene succinimides, diethyl 2-benzylidene succinate, or 2-benzylidene succinonitrile in the presence of an inorganic base has been investigated under solvent-free and ball-milling conditions. This protocol provides an expedient… read more here.
Keywords: fused cyclopentanes; mechanosynthesis photovoltaic; photovoltaic application; fullerene ... See more keywords
Electrochemical Benzylation of [60]Fullerene-Fused Lactones: Unexpected Formation of Ring-Opened Adducts and Their Photovoltaic Performance.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02635
Abstract: Electrochemical benzylation of [60]fullerene-fused lactones with different motifs unexpectedly affords three types of ring-opened benzylated adducts under different conditions. Both [60]fullerene-fused δ- and γ-lactones can be benzylated to generate ring-opened mono- and bis-benzylated adducts in… read more here.
Keywords: fullerene fused; benzylation fullerene; fused lactones; ring opened ... See more keywords
Palladium-catalyzed synthesis of [60]fullerene-fused benzofurans via heteroannulation of phenols.
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DOI: 10.1039/c6cc09080j
Abstract: Palladium-catalyzed heteroannulation of [60]fullerene with phenols has been developed as a practical and efficient protocol for the one-pot synthesis of various [60]fullerene-fused benzofurans. A possible reaction mechanism is proposed to explain the formation of C60-fused… read more here.
Keywords: fused benzofurans; fullerene fused; fullerene; heteroannulation ... See more keywords
Second-order nonlinear optical properties of [60]fullerene-fused dihydrocarboline derivates: a theoretical study on switch effect
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry C"
DOI: 10.1039/c9tc04126e
Abstract: The theoretical calculations show that [60]fullerene-fused dihydrocarboline derivatives exhibit significant first hyperpolarizability contrasts induced by their electrochemical feature. read more here.
Keywords: fullerene fused; second order; fused dihydrocarboline; order nonlinear ... See more keywords
Retro Baeyer-Villiger reaction: thermal conversion of the [60]fullerene-fused lactones to ketones.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00126h
Abstract: The conversion of the [60]fullerene-fused lactones to ketones with triflic anhydride as an unusual reductant under aerobic conditions has been achieved in excellent yields. The present thermal retro Baeyer-Villiger reaction from lactones to ketones has… read more here.
Keywords: fused lactones; fullerene; conversion fullerene; fullerene fused ... See more keywords