Fully‐Conjugated Covalent Organic Frameworks with Two Metal Sites for Oxygen Electrocatalysis and Zn–Air Battery
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Science"
DOI: 10.1002/advs.202206165
Abstract: Covalent organic frameworks (COFs) are a promising alternative toward catalysis, due to the unique framework structure and the excellent chemical stability. However, the scarcity of unsaturated metal sites and the low conductivity have constrained the… read more here.
Keywords: metal sites; organic frameworks; covalent organic; metal ... See more keywords
Random Copolymers Allow Control of Crystallization and Microphase Separation in Fully Conjugated Block Copolymers
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecules"
DOI: 10.1021/acs.macromol.8b01859
Abstract: Thin films of fully conjugated donor–acceptor block copolymers composed of an electron donating block and an electron accepting block can be used as single component photoactive layers in organic photovoltaic (OPV) devices. In order to realize… read more here.
Keywords: block; crystallization; fully conjugated; block copolymers ... See more keywords
Post-synthetic Fully π-Conjugated Three-Dimensional Covalent Organic Frameworks for High-Performance Lithium Storage.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c14813
Abstract: A fully π-conjugated nitrogen-rich three-dimensional covalent organic framework (PYTRI-COF-2) containing both pyrazine and triazine units was prepared through a post-synthetic strategy. The imine linkages in the pre-prepared PYTRI-COF-1 were converted into heterocyclic quinoline by the… read more here.
Keywords: dimensional covalent; post synthetic; three dimensional; covalent organic ... See more keywords
Fully Conjugated Donor–Acceptor Block Copolymers for Organic Photovoltaics via Heck–Mizoroki Coupling
Sign Up to like & getrecommendations! Published in 2019 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.8b00932
Abstract: The development of facile routes to prepare fully conjugated block copolymers (BCPs) from diverse monomers is an important goal for advancing robust bulk-heterojunction (BHJ) organic photovoltaics (OPVs). Herein we introduce a synthetic strategy for step-growth… read more here.
Keywords: mizoroki coupling; organic photovoltaics; block; block copolymers ... See more keywords
Three-Dimensional Fully π-Conjugated Macrocycles: When 3D-Aromatic and When 2D-Aromatic-in-3D?
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13478
Abstract: Several fully π-conjugated macrocycles with puckered or cage-type structures were recently found to exhibit aromatic character according to both experiments and computations. We examine their electronic structures and put them in relation to 3D-aromatic molecules… read more here.
Keywords: conjugated macrocycles; electron counts; three dimensional; aromatic aromatic ... See more keywords
Aromaticity in Fully π-Conjugated Open-Cage Molecules.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10859
Abstract: Although aromaticity in 2D π-conjugated monocyclic and polycyclic molecules has been intensively studied, aromaticity in 3D fully π-conjugated molecular cages remains largely unexplored mainly due to the synthetic challenges. Herein, we report the facile synthesis… read more here.
Keywords: conjugated open; aromaticity fully; cage; aromaticity ... See more keywords
Fully conjugated ladder polymers
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Science"
DOI: 10.1039/c7sc00154a
Abstract: Syntheses, properties and applications of fully conjugated ladder polymers are reviewed, together with an outlook to future opportunities and challenges. read more here.
Keywords: conjugated ladder; ladder polymers; fully conjugated;