Stereocontrolled Synthesis of the Fully Glycosylated Monomeric Unit of Lomaiviticin A.
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DOI: 10.1021/jacs.2c07631
Abstract: We describe a stereocontrolled synthesis of 3, the fully glycosylated monomeric unit of the dimeric cytotoxic bacterial metabolite (-)-lomaiviticin A (2). A novel strategy involving convergent, site- and stereoselective coupling of the β,γ-unsaturated ketone 6… read more here.
Keywords: glycosylated monomeric; stereocontrolled synthesis; synthesis; fully glycosylated ... See more keywords