Mechanochemical Access to Functional Clickates with Nitro-Retentive Selectivity via Organocatalyzed Oxidative Azide-Olefin Cycloaddition.
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DOI: 10.1021/acs.orglett.2c00621
Abstract: 4-Nitro-1,2,3-triazoles are crucial precursors for high energy materials, and their practical synthesis is a long-standing problem. Herein, we communicate a mechanochemical route for the selective synthesis of 4-nitro-1,2,3-triazoles via organocatalyzed oxidative [3 + 2] cycloaddition… read more here.
Keywords: mechanochemical access; via organocatalyzed; access functional; organocatalyzed oxidative ... See more keywords