Functional modeling of the MnCAT active site with a dimanganese(III) complex of an unsymmetrical polydentate N3O3 ligand.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2018.04.023
Abstract: A new diMnIII complex, [Mn2L(OAc)2(H2O)](BPh4)·3H2O (1), obtained with the unsymmetrical N3O3-ligand H3L = 1-[N-(2-pyridylmethyl),N-(2-hydroxybenzyl)amino]-3-[N'-(2-hydroxybenzyl),N'-(benzyl)amino]propan-2-ol, has been prepared and characterized. The unsymmetrical hexadentate ligand L3- leads to coordination dissymmetry (dissimilar donor atoms) around each Mn ion (N2O4 and… read more here.
Keywords: n3o3 ligand; modeling mncat; mncat active; active site ... See more keywords
Cost-effective concept development using functional modeling guidelines
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DOI: 10.1016/j.rcim.2018.01.007
Abstract: Abstract Functional modeling provides a formal approach to early concept development by directly translating customer needs into desired product behavior. By first developing product functionality, the gap between customer needs and product form is lessened.… read more here.
Keywords: product; functional modeling; cost effective; concept development ... See more keywords
Bioinorganic Chemistry on Electrodes: Methods to Functional Modeling.
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DOI: 10.1021/jacs.2c01842
Abstract: One of the major goals of bioinorganic chemistry has been to mimic the function of elegant metalloenzymes. Such functional modeling has been difficult to attain in solution, in particular, for reactions that require multiple protons… read more here.
Keywords: bioinorganic chemistry; chemistry electrodes; chemistry; methods functional ... See more keywords