Operator inequalities, functional models and ergodicity
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Mathematical Analysis and Applications"
DOI: 10.1016/j.jmaa.2021.124984
Abstract: Abstract We discuss when an operator T, subject to a rather general inequality in hereditary form, admits a unitarily equivalent functional model of Agler type in the reproducing kernel Hilbert space associated to the inequality.… read more here.
Keywords: operator; inequalities functional; functional models; models ergodicity ... See more keywords
Functional models of nonheme diiron enzymes: reactivity of the μ-oxo-μ-1,2-peroxo-diiron(iii) intermediate in electrophilic and nucleophilic reactions.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04551a
Abstract: The reactivity of the previously reported peroxo-adduct [FeIII2(μ-O)(μ-1,2-O2)(IndH)2(solv)2]2+ (1) (IndH = 1,3-bis(2-pyridyl-imino)isoindoline) has been investigated in nucleophilic (e.g., deformylation of alkyl and aryl alkyl aldehydes) and electrophilic (e.g. oxidation of phenols) stoichiometric reactions as biomimics… read more here.
Keywords: functional models; models nonheme; peroxo; nonheme diiron ... See more keywords
A review on bio-functional models of catechol oxidase probed by less explored first row transition metals
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2022.2122053
Abstract: Abstract Catecholase activity is a biological process in which type-3 active site of a copper enzyme, named catechol oxidase, catalyzes oxidation of o-diphenolic substrates to the corresponding o-quinones coupled with reduction of molecular dioxygen into… read more here.
Keywords: row transition; first row; functional models; catechol oxidase ... See more keywords
Constructing functional models from biophysically-detailed neurons
Sign Up to like & getrecommendations! Published in 2022 at "PLoS Computational Biology"
DOI: 10.1371/journal.pcbi.1010461
Abstract: Improving biological plausibility and functional capacity are two important goals for brain models that connect low-level neural details to high-level behavioral phenomena. We develop a method called “oracle-supervised Neural Engineering Framework” (osNEF) to train biologically-detailed… read more here.
Keywords: functional models; neuron models; models biophysically; constructing functional ... See more keywords