EPR and 31P ENDOR Characterization of Pseudo-Jahn-Teller Dynamics and N2 Activation in Functional Nitrogenase Models, P3EM(N2) (M = Fe, Co; E = Si, B, C).
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DOI: 10.1021/acs.inorgchem.5c02760
Abstract: The nominally trigonal, pseudo-Jahn-Teller (PJT)-active, S = 1/2 N2-bound complexes, P3EM(N2), M = Fe, Co, with three in-plane phosphine ligands and axial donors, E = Si, B, C, include functional nitrogenase models that catalyze the… read more here.
Keywords: jahn teller; functional nitrogenase; pseudo jahn; 31p endor ... See more keywords