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   Articles with "functionalisation" as a keyword



Biocatalytic Amino Acid Functionalisation

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recommendations! Published in 2024 at "ChemMedChem"

DOI: 10.1002/cmdc.202400628

Abstract: The success of new therapeutic modalities relies on advancements in synthetic chemistry to produce compounds for evaluation throughout the drug discovery process. The use of non‐canonical amino acids (ncAAs) allows the properties of peptide drugs… read more here.

Keywords: biocatalytic amino; acid functionalisation; amino acids; functionalisation ... See more keywords

Biopolymer catalyst for biodiesel production by functionalisation of radiation grafted flax fibres with diethylamine under optimised conditions

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recommendations! Published in 2019 at "Radiation Physics and Chemistry"

DOI: 10.1016/j.radphyschem.2019.108375

Abstract: Abstract A biopolymer-based catalyst with an alkaline moiety was prepared by radiation induced grafting (RIG) of glycidylmethaacrylate (GMA) onto flax fibres followed by functionalisation with diethyl amine (DEA) and treatment with NaOH. The density of… read more here.

Keywords: flax fibres; catalyst; radiation; biodiesel production ... See more keywords

Impact of heteroatoms and chemical functionalisation on crystal structure and carrier mobility of organic semiconductors

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recommendations! Published in 2024 at "npj Computational Materials"

DOI: 10.1038/s41524-024-01397-1

Abstract: The substitution of heteroatoms and the functionalisation of molecules are established strategies in chemical synthesis. They target the precise tuning of the electronic properties of hydrocarbon molecules to improve their performance in various applications and… read more here.

Keywords: crystal structure; mobility; structure; carrier ... See more keywords
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Progress and perspectives on directing group-assisted palladium-catalysed C-H functionalisation of amino acids and peptides.

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recommendations! Published in 2021 at "Chemical Society reviews"

DOI: 10.1039/d0cs01441a

Abstract: Peptide modifications can unlock a variety of compounds with structural diversity and abundant biological activity. In nature, peptide modifications, such as functionalisation at the side-chain position of amino acids, are performed using post-translational modification enzymes… read more here.

Keywords: functionalisation; amino acids; selective activation; directing group ... See more keywords

Halogenases: a palette of emerging opportunities for synthetic biology–synthetic chemistry and C–H functionalisation

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recommendations! Published in 2021 at "Chemical Society Reviews"

DOI: 10.1039/d0cs01551b

Abstract: The enzymatic generation of carbon–halogen bonds is a powerful strategy used by both nature and synthetic chemists to tune the bioactivity, bioavailability and reactivity of compounds, opening up the opportunity for selective C–H functionalisation. Genes… read more here.

Keywords: functionalisation; synthetic biology; chemistry; palette emerging ... See more keywords

Boronic acids for functionalisation of commercial multi-layer graphitic material as an alternative to diazonium salts

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recommendations! Published in 2020 at "New Journal of Chemistry"

DOI: 10.1039/d0nj04187d

Abstract: A novel radical-based functionalisation strategy for the synthesis of functionalised commercially obtained plasma-synthesised multi-layer graphitic material (MLG) is presented herein. 4-(trifluoromethyl)phenyl boronic acid was utilised as a source of 4-(trifluoromethyl)phenyl radicals to covalently graft upon… read more here.

Keywords: graphitic material; layer graphitic; functionalisation; multi layer ... See more keywords
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Effect of linker functionalisation on the catalytic properties of Cu nanoclusters embedded in MOFs in direct CO and CO2 reduction by H2.

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recommendations! Published in 2021 at "Faraday discussions"

DOI: 10.1039/d1fd00012h

Abstract: Metal-organic frameworks are promising host supporting matrices for catalytically active guests. In particular, their crystallinity renders them desirable as their pores may act as atom-precise templates for the growth of nanoparticles or nanoclusters therein. This… read more here.

Keywords: effect linker; functionalisation catalytic; functionalisation; effect ... See more keywords

N-Heterocyclic carbenes as privileged ligands for nickel-catalysed alkene functionalisation.

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recommendations! Published in 2023 at "Chemical Society reviews"

DOI: 10.1039/d2cs00972b

Abstract: Alkene functionalisation is a powerful strategy that has enabled access to a wide array of compounds including valuable pharmaceuticals and agrochemicals. The reactivity of the alkene π-bond has allowed incorporation of a diverse range of… read more here.

Keywords: functionalisation; carbenes privileged; catalysed alkene; alkene functionalisation ... See more keywords

Recent advances in the remote catalytic functionalisation of ferrocenes.

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recommendations! Published in 2024 at "Dalton transactions"

DOI: 10.1039/d4dt02246g

Abstract: While the catalytic activation of C-H bonds adjacent to a directing group is well developed in the ferrocene series, the functionalisation of a remote position has scarcely been explored. Here, we summarise the latest developments… read more here.

Keywords: advances remote; catalytic functionalisation; functionalisation ferrocenes; functionalisation ... See more keywords

Green Innovations in C–H Bond Functionalisation: Exploring Homogeneous Recyclable Catalytic Systems

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recommendations! Published in 2025 at "Green Chemistry"

DOI: 10.1039/d5gc00278h

Abstract: C–H bond functionalisation is a pivotal tool in contemporary fabrication of organic compounds, which enables straight transformation of inert C–H bonds exempt from needing pre-functionalisation. Homogeneous recyclable catalytic systems upsurge... read more here.

Keywords: homogeneous recyclable; functionalisation; catalytic systems; recyclable catalytic ... See more keywords

Surface passivation and functionalisation for mass photometry

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recommendations! Published in 2024 at "Journal of Microscopy"

DOI: 10.1111/jmi.13302

Abstract: Interferometric scattering (iSCAT) microscopy enables the label‐free observation of biomolecules. Consequently, single‐particle imaging and tracking with the iSCAT‐based method known as mass photometry (MP) is a growing area of study. However, establishing reliable cover glass… read more here.

Keywords: passivation functionalisation; mass photometry; surface; functionalisation ... See more keywords