Regio- and stereoselective functionalization of alkenes with emphasis on mechanistic insight and sustainability concerns
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Saudi Chemical Society"
DOI: 10.1016/j.jscs.2021.101260
Abstract: Abstract Alkene is an attractive substrate for chemists due to its easy availability and reactivity towards large number of reactants affording diverse range of organic compounds. It reacts under ionic and free radical mechanisms including… read more here.
Keywords: alkenes emphasis; functionalization; regio stereoselective; stereoselective functionalization ... See more keywords
Selective Functionalization of Alkenes and Alkynes by Dinuclear Manganese Catalysts.
Sign Up to like & getrecommendations! Published in 2024 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.4c00385
Abstract: ConspectusAlkenes and alkynes are fundamental building blocks in organic synthesis due to their commercial availability, bench-stability, and easy preparation. Selective functionalization of alkenes and alkynes is a crucial step for the synthesis of value-added compounds.… read more here.
Keywords: selective functionalization; functionalization alkenes; manganese catalysts; dinuclear manganese ... See more keywords
Cu-Catalyzed Relay Functionalization of Alkenes: Diverse Synthesis of Diazidated Quinazolinones and Polycyclic Imidazoles.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.4c04353
Abstract: A Cu-catalyzed relay process for the preparation of diazidated quinazolinone and polycyclic imidazole derivatives in which readily available alkene-tethered substrates undergo an addition/cyclization/C(sp3)-H functionalization of alkene sequences with high efficiency is described. Various functionalized N-heteropolycyclic… read more here.
Keywords: functionalization alkenes; catalyzed relay; functionalization; relay functionalization ... See more keywords
Mechanistic Studies on the Anodic Functionalization of Alkenes Catalyzed by Diselenides
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b01236
Abstract: Herein, we present a detailed kinetic and thermodynamic analysis of the anodic allylic esterification of alkenes as well as the bulk application of the anodic amination and esterification of nonact... read more here.
Keywords: studies anodic; alkenes catalyzed; mechanistic studies; anodic functionalization ... See more keywords
Radical-Mediated Strategies for the Functionalization of Alkenes with Diazo Compounds.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c05183
Abstract: One of the most common reactions of diazo compounds with alkenes is cyclopropanation that occurs through metal carbene or free carbene intermediates. Alternative functionalization of alkenes with diazo compounds is limited, and methodology for the… read more here.
Keywords: carbon; diazo compounds; radical mediated; alkenes diazo ... See more keywords
Recent Development of Single-Atom Catalysis for the Functionalization of Alkenes
Sign Up to like & getrecommendations! Published in 2023 at "Catalysts"
DOI: 10.3390/catal13040730
Abstract: The functionalization of alkenes is one of the most important conversions in synthetic chemistry to prepare numerous fine chemicals. Typical procedures, such as hydrosilylation and hydroformylation, are traditionally catalyzed using homogeneous noble metal complexes, while… read more here.
Keywords: atom; single atom; atom catalysis; functionalization alkenes ... See more keywords
Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes
Sign Up to like & getrecommendations! Published in 2018 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.14.154
Abstract: Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as mCPBA are employed to in situ generate… read more here.
Keywords: iii; hypervalent iodine; iii catalyzed; iodine iii ... See more keywords