Catalytically Relevant Intermediates in the Ni-Catalyzed C(sp2)-H and C(sp3)-H Functionalization of Aminoquinoline Substrates.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b09109
Abstract: This Article describes the synthesis and characterization of cyclometalated aminoquinoline NiII σ-aryl and σ-alkyl complexes that have been proposed as key intermediates in Ni-catalyzed C-H functionalization reactions. These NiII complexes serve as competent catalysts for… read more here.
Keywords: catalytically relevant; niiii species; functionalization aminoquinoline; intermediates catalyzed ... See more keywords
Three-component ruthenium-catalyzed remote C-H functionalization of 8-aminoquinoline amides.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc05491g
Abstract: Multicomponent reactions can efficiently construct complex molecular structures from simple precursors. Herein, a novel ruthenium-catalyzed three-component highly selective remote C-H functionalization of 8-aminoquinoline amides has been described. The reaction tolerates a wide range of functional… read more here.
Keywords: functionalization aminoquinoline; remote functionalization; aminoquinoline amides; three component ... See more keywords