Organocatalytic Cascade β-Functionalization/Aromatization of Pyrrolidines via Double Hydride Transfer.
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DOI: 10.1021/acs.orglett.9b03918
Abstract: An unprecedented cascade β-functionalization/aromatization reaction of N-arylpyrrolidines was established. A series of β-substituted arylpyrroles embedded with trifluoromethyl groups are provided directly from N-arylpyrrolidines. The deuterium-labeling experiments indicate that sequential double hydride transfer processes serve as… read more here.
Keywords: double hydride; hydride transfer; functionalization aromatization; cascade functionalization ... See more keywords