Palladium-Catalyzed Redox-Neutral N-O/C(sp3)-H Functionalization of Aryl Oximes with Isocyanides.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.6b03852
Abstract: A redox-neutral palladium-catalyzed N-O/C(sp3)-H functionalization of aryl oximes with isocyanides has been developed. Various pyrrole derivatives were prepared in good to excellent yields through oxime carbamate as a key intermediate and internal oxidant in this… read more here.
Keywords: sp3 functionalization; functionalization aryl; redox neutral; palladium catalyzed ... See more keywords
Chelation-assisted α and β C–H functionalization of aryl alkenes with alkynes and alkenes
Sign Up to like & getrecommendations! Published in 2024 at "Organic Chemistry Frontiers"
DOI: 10.1039/d4qo00325j
Abstract: α C–H alkenylation of aryl alkenes by six-membered exo-palladacycles was demonstrated to afford aryl dienes, which underwent β C–H alkenylation through seven-membered endo-palladacycles to produce aryl trienes with excellent E/Z ratio selectivity. read more here.
Keywords: aryl alkenes; functionalization aryl; chelation assisted; aryl ... See more keywords