Large-scale, green, and high-efficiency exfoliation and noncovalent functionalization of fluorinated graphene by ionic liquid crystal
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2020.125104
Abstract: Abstract In this study, green and high-efficient ionic liquids crystal (ILC)-assisted hydrothermal exfoliation method was developed for exfoliation and functionalization of fluorinated graphene (FG). The proposed method was efficient for exfoliating FG from bulk fluorinated… read more here.
Keywords: fluorinated graphene; green high; exfoliation; noncovalent functionalization ... See more keywords
Selective Metalation and Functionalization of Fluorinated Nitriles Using 2,2,6,6-Tetramethylpiperidyl Bases.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c02572
Abstract: We have accomplished regioselective deprotometalation of aromatic and heteroaromatic nitriles via (TMP)2Zn·2MgCl2·2LiCl and TMPMgCl·LiCl (TMP = 2,2,6,6-tetramethylpiperidyl) with the exploration of new and scarcely investigated metalation positions. Regioselectivity was rationalized by DFT calculations. The quenching… read more here.
Keywords: metalation; metalation functionalization; tetramethylpiperidyl; fluorinated nitriles ... See more keywords