Remote Functionalization of Inert C(sp3)-H Bonds via Dual Catalysis Driven by Alkene Hydrofluoroalkylation Using Industrial Feedstocks.
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DOI: 10.1021/acs.orglett.4c02901
Abstract: We have developed a dual-catalytic system capable of site-selective azidation of inert C(sp3)-H bonds with concomitant and modular anti-Markovnikov alkene fluoroalkylation. The protocol leverages the synergetic cooperation of both the photocatalyst and earth-abundant iron catalyst… read more here.
Keywords: bonds via; remote functionalization; functionalization inert; sp3 bonds ... See more keywords