To “Rollover” or Not? Stereoelectronically Guided C–H Functionalization Pathways from Rhodium–Abnormal NHC Intermediates
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DOI: 10.1021/acsomega.7b01846
Abstract: Rollover C–H activation with transition-metal complexes has been found to be a difficult but viable pathway to functionalize potentially chelating molecules, which are otherwise reluctant to react further. However, selective rollover or nonrollover C–H activation… read more here.
Keywords: functionalization pathways; rollover; guided functionalization; rollover stereoelectronically ... See more keywords