Iron-catalyzed oxidative functionalization of C(sp3)-H bonds under bromide-synergized mild conditions.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03939b
Abstract: An efficient oxidation and functionalization of C-H bonds with an inorganic-ligand supported iron catalyst and hydrogen peroxide to prepare the corresponding ketones was achieved using the bromide ion as a promoter. Preliminary mechanistic investigations indicated… read more here.
Keywords: oxidative functionalization; iron catalyzed; sp3 bonds; functionalization sp3 ... See more keywords
Metal-free polyporphyrin based photocatalysts for the functionalization of C(sp3)-H bonds in water.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04352a
Abstract: The development of metal-free and water-compatible photocatalysts for visible light-induced environmentally friendly transformation in water is highly desirable. Herein, two types of polyporphyrin based heterogeneous photocatalysts with different water-solubility in water, namely, an insoluble polymer… read more here.
Keywords: polyporphyrin based; metal free; water; free polyporphyrin ... See more keywords