Facile in Situ Halogen Functionalization via Triple-Bond Hydrohalogenation: Enhancing Sorption Capacities through Halogenation to Halofumarate-Based Zr(IV)-Metal-Organic Frameworks
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DOI: 10.1021/acs.chemmater.9b00524
Abstract: Surface halogenation is an important means to tune or improve functionalities of solid-state materials. However, this concept has been hardly explored and exploited in the engineering of metal-orga... read more here.
Keywords: situ halogen; halogen functionalization; metal; functionalization via ... See more keywords
C–H Functionalization via Electrophotocatalysis and Photoelectrochemistry: Complementary Synthetic Approach
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DOI: 10.1021/acssuschemeng.0c08434
Abstract: Photoelectrochemical (PEC) cells are well documented as an important tool for energy and environmental applications. Most commonly used to produce hydrogen fuel from water splitting, PEC cells have also been directed toward pollutant degradation, carbon… read more here.
Keywords: electrophotocatalysis photoelectrochemistry; via electrophotocatalysis; electrochemistry; functionalization ... See more keywords
Mechanism of Z-Selective Allylic Functionalization via Thianthrenium Salts.
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DOI: 10.1021/jacs.4c00682
Abstract: A detailed mechanistic study of the Z-selective allylic functionalization via thianthrenium salts is presented. Kinetic analyses, deuterium labeling experiments, and computational methods are used to rationalize the observed reactivity and selectivity. We find that the… read more here.
Keywords: via thianthrenium; selective allylic; thianthrenium salts; thianthrenium ... See more keywords
Remote ortho-C-H functionalization via medium-sized cyclopalladation.
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DOI: 10.1039/d1cc05310h
Abstract: Compared to the tremendous progress made in directed ortho-C-H functionalization via five- or six-membered cyclopalladation, protocols with the ability to selectively activate more remote C-H bonds through the intermediacy of larger, less favorable, seven- or… read more here.
Keywords: functionalization via; cyclopalladation; ortho functionalization; via medium ... See more keywords
Site-Selective Late-Stage C–H Functionalization via Thianthrenium Salts
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DOI: 10.1055/s-0040-1706034
Abstract: The high abundance of C–H bonds in organic molecules makes C–H functionalization a powerful approach to quickly increase the complexity of an organic molecule. However, the high abundance of C–H bonds also provides a challenge… read more here.
Keywords: functionalization; sulfonium; functionalization via; site selective ... See more keywords
Erratum: Facile Functionalization via Plasma-Enhanced Chemical Vapor Deposition for the Effective Filtration of Oily Aerosol. Polymers 2019, 11, 1490
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DOI: 10.3390/polym12061422
Abstract: The authors wish to make a change to the published paper [...]. read more here.
Keywords: facile functionalization; via plasma; erratum facile; functionalization via ... See more keywords