Functionalized Aromatic Dicarboxylate Ligands in Uranyl-Organic Assemblies: The Cases of Carboxycinnamate and 1,2-/1,3-Phenylenedioxydiacetate.
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DOI: 10.1021/acs.inorgchem.9b03273
Abstract: 2-Carboxycinnamic acid (ccnH2) and the isomeric 1,2- and 1,3-phenylenedioxydiacetic acids (1,2- and 1,3-pddaH2) have been used to synthesize eight uranyl ion complexes under solvo-hydrothermal conditions. In the four complexes [PPh4]2[UO2(ccn)(NO3)]2 (1), [PPh4]2[UO2(ccn)(dibf)]2 (2), [UO2(ccn)(bipy)]2 (3),… read more here.
Keywords: ccn; carboxylate; uo2 ccn; functionalized aromatic ... See more keywords