Synthesis of selenoether and thioether functionalized bicyclo[1.1.1]pentanes
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DOI: 10.1016/j.tet.2020.131692
Abstract: Abstract Bicyclo[1.1.1]pentane is widely recognized as the bioisostere for aryl, tert-butyl, and internal alkynes. Herein we report an efficient and practical method for the preparation of selenoether and thioether functionalized bicyclo[1.1.1]pentanes from selenosulfonates/thiosulfonates and propellane.… read more here.
Keywords: bicyclo pentanes; selenoether thioether; functionalized bicyclo; thioether functionalized ... See more keywords
Disproportionation-Inspired Construction of Highly Functionalized Bicyclo[3.2.1]octanes.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00397
Abstract: The formation of one unavoidable byproduct in traditional disproportionation reactions limits their applications in synthesis. Inspired by convergent disproportionation, we develop an iodine-induced cyclization and oxidation of allylic alcohols to produce highly functionalized bicyclo[3.2.1]octanes through… read more here.
Keywords: highly functionalized; disproportionation inspired; functionalized bicyclo; bicyclo octanes ... See more keywords