Kinetic resolution via supramolecular iminium catalysis: multiactivation enables the asymmetric synthesis of β-aryl substituted aldehydes and densely functionalized cyclohexanes.
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DOI: 10.1039/c7cc01625e
Abstract: The kinetic resolution of β-aryl substituted 1,7-dioxo compounds with α,β-unsaturated aldehydes affording enantioenriched β-aryl substituted aldehydes as well as densely functionalized cyclohexanes is presented. The two enantioenriched products were obtained in reasonable yields with high… read more here.
Keywords: aryl substituted; functionalized cyclohexanes; kinetic resolution; densely functionalized ... See more keywords