Novel multi-functionalized fluorine-containing organometallics: Preparation and applications of tetrafluoroethylenated zinc reagent
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2021.109781
Abstract: Abstract On treating 2,4-dibromo-3,3,4,4-tetrafluorobut-1-ene, readily prepared from commercially available 4‑bromo-3,3,4,4-tetrafluorobut-1-ene (1), with 2.0 eq. of zinc-silver alloy at 40 °C in CH3CN, zinc insertion at the terminal C(sp3)–Br site proceeded selectively, giving the corresponding (3‑bromo-1,1,2,2-tetrafluorobut-3-en-1-yl)zinc bromide… read more here.
Keywords: novel multi; containing organometallics; functionalized fluorine; reagent ... See more keywords