New Nickel-Based Catalytic System with Pincer Pyrrole-Functionalized N-Heterocyclic Carbene as Ligand for Suzuki-Miyaura Cross-Coupling Reactions
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.122068
Abstract: Abstract A new catalytic system with Ni(NO3)2ยท6H2O as the catalyst and a pincer pyrrole-functionalized N-heterocyclic carbene as the ligand was employed in the Suzuki-Miyaura cross-coupling reactions of aryl iodides with arylboronic acids. With 5 mol%… read more here.
Keywords: pyrrole functionalized; system; catalytic system; pincer pyrrole ... See more keywords
Functionalized N-Heterocyclic Carbene Monolayers on Gold for Surface-Initiated Polymerizations.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c10985
Abstract: Although N-heterocyclic carbenes (NHCs) are superior to thiol adsorbates in that they form remarkably stable bonds with gold, the generation of NHC-based self-assembled monolayers (SAMs) typically requires a strong base and an inert atmosphere, which… read more here.
Keywords: functionalized heterocyclic; adsorbate; spectroscopy; surface initiated ... See more keywords
Cyclooctyne-Functionalized N-Heterocyclic Carbenes for Click Coupling of Sensing Oligonucleotides to Gold Surfaces.
Sign Up to like & getrecommendations! Published in 2025 at "ACS sensors"
DOI: 10.1021/acssensors.5c01548
Abstract: Nucleic acid-based sensors (NBEs) are used for biomolecular detection and can enable continuous, real-time molecular monitoring in vivo. NBEs are typically constructed via thiol self-assembled monolayers (SAMs) on gold electrodes, consisting of redox-reporter-modified oligonucleotides diluted… read more here.
Keywords: coupling sensing; heterocyclic carbenes; cyclooctyne functionalized; click coupling ... See more keywords
Bidentate Donor-Functionalized N-Heterocyclic Carbenes: Valuable Ligands for Ruthenium-Catalyzed Transfer Hydrogenation
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27154703
Abstract: Ruthenium complexes are by far the most studied compounds that catalyze hydrogen transfer reactions. In this review, we describe the use in this field of ruthenium complexes bearing bidentate donor-functionalized N-heterocyclic carbene ligands. The review… read more here.
Keywords: donor functionalized; functionalized heterocyclic; transfer hydrogenation; transfer ... See more keywords