Convergent Synthesis of Functionalized Indolines from Alkyl Aryl Tertiary Amines and Diazoesters via Visible Light-Driven [4 + 1]-Annulation Approach.
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DOI: 10.1021/acs.orglett.5c02530
Abstract: We report the synthesis of functionalized indolines via α-amino radical/iminium ion through the visible-light-induced SET and HAT mediated [4 + 1]-annulation strategy between alkyl aryl tertiary amines and diazoesters. The unique role of diazoester in… read more here.
Keywords: alkyl aryl; visible light; synthesis functionalized; aryl tertiary ... See more keywords
Easy Access to Functionalized Indolines and Tetrahydroquinolines via a Photochemical Cascade Cyclization Reaction.
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DOI: 10.1021/jacs.4c00962
Abstract: Herein, the development of a light-mediated synthesis of functionalized indolines and tetrahydroquinolines is reported. These structural motifs are considered as highly valuable targets, attributed to their widespread occurrence in pharmaceuticals and natural products. The gold-mediated… read more here.
Keywords: reaction; cyclization reaction; functionalized indolines; cascade cyclization ... See more keywords